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Alloys 200 and 201

Alloy 200 (UNS N02200) is an unalloyed wrought nickel. It offers excellent corrosion resistance, good mechanical, magnetic and magnetostrictive properties and useful thermal and electrical conductivities.

Alloy 201 (UNS N02201), with reduced carbon content(0.02% max), shows better corrosion resistance at elevated temperatures above 300°C (570°F) by avoiding graphite precipitation.

These alloys are characterised by:

  • excellent corrosion resistance in many alkaline media
  • good mechanical properties within a wide range of temperatures
  • magnetization decreasing continuously between -273 and 360°C (-458 and 680°F) and showing paramagnetism above the Curie point

Designation and Standards

Country National Standard Material Designation Specification
Chem. composition Tube and pipe Sheet and plate Rod and bar Strip Wire Forgings
seamless welded
France AFNOR
Germany DIN VdTÜV2) W.-Nr. 2.4066 Ni 99.2 W.-Nr. 2.4068 LC-Ni 99 17740 345 17751 345 177511) 17750 345 17752 345 17750 345 17753 17754 345
United Kingdom BS NA11 NA12 3074 3072 3076 3073 3075
USA ASTM ASME AMS UNS N02200 N02201 B161/163 SB161/163 B725/730 B162 SB162 5553 2 ) B160 SB160 5553 2 ) B162 SB162 B564 SB564
ISO Ni 99.0 LC-Ni 99.0

1) Ni 99.2 only 2) LC-Ni 99 only

Chemical Composition (%)

Alloy 200 Ni Fe C Mn Si Cu Mg Ti Si
min 99.2 - - - - - - - -
max - 0.4 0.10 0.3 0.1 0.25 0.05 - 0.005
Alloy 201 Ni Fe C Mn Si Cu Mg Ti Si
min 99.2 - - - - - - 0.01 -
max - 0.4 0.02 0.3 0.1 0.25 0.05 0.10 0.005

Mechanical Properties

The following mechanical properties are applicable to Alloys 200 & 201 in the indicated forms and size ranges and in the annealed condition (unless otherwise specified). Material outside these size ranges with agreed properties is subject to special enquiry

Sheet and plate up to 50mm 2 in
Strip 0.3 to 3mm 0.012 to 0.12 in
Rod and bar up to 250mm 10 in
Forgings up to 150mm 6 in
Tube and pipe wall 1 to 12.5mm 0.04 to 0.5 in
Diameter 6 to 275mm 0.25 to 11 in
According to spec. Condition Tensile strength 0.2% Yield 1.0% Yield strength Elong A5 %
N/mm2 ksi strength ksi N/mm2 ksi
Alloy 200 DIN 17750-54 annealed ≥ 380 ≥ 55 ≥ 100 ≥ 14.5 ≥ 125 ≥ 18.1 ≥ 40
ASTM B 160-163, 725, 730 annealed ≥ 380 ≥ 55 ≥ 105 ≥ 15 - - ≥ 40
stress rel. ≥ 450 ≥ 65 ≥ 275 ≥ 40 - - ≥ 15
Typical values annealed 440 63.8 150 21.8 180 26.1 44
Alloy 201 DIN 17750-54, VdTÜV 345 annealed ≥ 340 ≥ 49.3 ≥ 80 ≥ 11.6 ≥ 105 ≥ 15 ≥ 40
ASTM B 160-163, 725, 730 annealed ≥ 345 ≥ 50 ≥ 80 ≥ 12 - - ≥ 40
annealed ≥ 415 ≥ 60 ≥ 205 ≥ 30 - - ≥ 15
Typical values annealed ≥ 415 60 125 18.1 150 21.8 47

Some standards show greater deviations for 0.2% yield values Mechanical properties at room temperature Please Note: The figures quoted are intended for guidance only. For further information, please refer to the standards listed or contact our sales or QA Departments.

Metallurgical Structure

Alloys 200 and 201 have face-centred cubic structures between temperatures close to absolute zero and melting point.

Corrosion Resistance

Alloys 200 and 201 have excellent resistance to many corrosive media from acid to alkaline. They are most useful under reducing conditions but, where a passive oxide is formed, they may also be used in oxidising conditions.

Their most significant property is extremely high resistance to caustic alkalies up to and including the molten state. The extra-low carbon content of Alloy 201 gives virtual immunity to intergranular attack above about 315°C (600°F). The presence of chlorates must be kept to a minimum, as they accelerate the rate of attack.

The resistance of Alloys 200 and 201 to mineral acids varies according to temperature and concentration and whether or not the solution is aerated. Corrosion resistance is better in deaerated acid.

In acid, alkaline and neutral salt solutions, Alloys 200 and 201 show good resistance, but severe attack occurs in oxidising salt solutions. Both alloys are resistant to all dry gases at room temperature. The low-carbon alloy can be used in dry chlorine and hydrogen chloride -at temperatures up to 550°C (1020°F).

Applications

Unalloyed wrought nickel combines excellent mechanical properties with good corrosion resistance. Above 300°C (570°F) working temperature, the low carbon version is efficient. The limited carbon content lowers mechanical, values and work-hardening rate but promotes ductility.

Typical applications include:

• food production, such as handling of cooling brines, fatty acids and fruit juices
-resistance to acid, alkaline and neutral salt solutions and to organic acids

Typical applications continued:

• vessels in which fluorine is generated and reacted with hydrocarbons -resistance to fluorine • storing and transportation of phenol -immunity from any form of attack ensures absolute product purity
• manufacture and handling of sodium hydroxide, particularly at temperatures above 300°C (570°F). Typical industries where sodium hydroxide is used are the:

-production of viscose rayon and manufacture of soap - general corrosion resistance and virtual immunity to intergranular attack above 315°C (600°F)
-production of hydrochloride and chlorination of hydrocarbons such as benzene, methane and ethane - resistance at elevated temperatures to dry chlorine and hydrogen chloride -manufacture of vinyl chloride monomer - resistance to hydrogen chloride at elevated temperatures

Stock Size Range

Alloy 200/201- Bar, Tube, Pipe and Fittings

Bar mm dia Tube mm o/d Pipe nb sch10 - sch80 Seamless fittings nb
6.35 - 152.4 6.35 - 25.4 1/2” - 6” 1/2” - 6”

Alloy 200/201 - Sheet and Plate

Size 2m x 1m 8’ x 4’ 2.5m x 1.25m 3m x 1.2m 3m x 1.5m
Thickness 1.6mm 3, 4, 5, 6mm 11/2, 2” 2, 3mm 2, 3, 4, 5, 6mm
Size 10’ x 5’ 4m x 2m 6m x 2m 6.096m x 2.438m
Thickness 1/2”, 3/4”, 1”, 11/4” 2, 3, 4, 5, 6, 8, 10mm - -

The above tables represent our standard stock range.
Other sizes can be manufactured to order, often with short lead times.

Alloy 400

Alloy 400 (UNS N04400) is a single-phase solid-solution nickelcopper alloy with excellent corrosion resistance to a wide range of media

This alloy is characterised by:

  • corrosion resistance in a wide range of marine and chemical environments
  • freedom from chloride induced stress-corrosion cracking
  • good mechanical properties from sub-zero temperatures up to about 550°C(1020°F)
  • approval for pressure vessels with wall temperatures from -10 to 425°C (14 to 800°F) according to VdTÜV-Wbl.263 and up to 900°F (480°C) according to ASME Boiler and Pressure Vessel Code
  • good workability and weldability

Designation and Standards

Country National Standard Material Designation Specification
Chem. composition Tube and pipe Sheet and plate Rod and bar Strip Wire Forgings
seamless welded
France AFNOR NU30
Germany DIN VdTÜV2) W.-Nr.2.4360 NiCu30Fe 17743 263 17751 263 17750 263 17752 263 17750 263 17753 17754 263
United Kingdom BS NA 13 3074 3072 3076 3073 3075
USA ASTM ASME ASME AMS Code case QQ-N-281 UNS N04400 Table 1 B163/ 165 SB163/ 165 4574 B127 SB127 4544 Form 4,6 B164 SB164 4675 Form 1 B127 SB127 Form 5 Form 7 B564 SB564 4675 Form 2
ISO NiCu30 9722 6207 6208 9723 6208 9724 9725

Chemical Composition(%)

Alloy 400 Ni Fe C Mn Si Cu Al S
min 63.0 1.0 - - - 28.0 - -
max - 2.5 0.15 1.25 0.5 34.0 0.5 0.02

Mechanical Properties

The following properties are applicable to Alloy 400 in the stated conditions

and specifications. Specified properties of material outside these ranges are subject to special enquiry.

Condition Specification Tensile strength 0.2% Yield Strength 1.0% Yield Strength Elong A5 % Brinell hardness HB
N/mm2 ksi N/mm2 ksi N/mm2 ksi
Annealed DIN, VdTÜV - Wbl. 450 65 180 26 210 30 35 ≤ 150
ASTM, ASME, QQ-N, BS 480 70 195 28 220* 35 -
Stress Relieved DIN 550 80 300 44 25 ~170
VdTÜV-Wbl. 580 84 400 58 18 -
ASTM, ASME, BS 550 600 80 87 275415 40 60 20